Components of the force and quantum numbers

But before we proceed, we will look into specific quantum numbers of the relative system and study expectation vaues of the various terms of $$ V(\mathbf{r})= \left\{ C_c + C_\mathbf{\sigma} \mathbf{\sigma}_1\cdot\mathbf{\sigma}_2 + C_T \left( 1 + {3\over m_\alpha r} + {3\over \left(m_\alpha r\right)^2}\right) S_{12} (\hat r)\right. $$ $$ \left. + C_{SL} \left( {1\over m_\alpha r} + {1\over \left( m_\alpha r\right)^2} \right) \mathbf{L}\cdot \mathbf{S} \right\} \frac{e^{-m_\alpha r}}{m_\alpha r} $$