What follows now is a more technical discussion on how we can solve the two-nucleon problem. This will lead us to the so-called Lippman-Schwinger equation for the scattering problem and a rewrite of Schroedinger's equation in relative and center-of-mass coordinates.
Before we break down the Schroedinger equation into a partial wave decomposition, we derive now the so-called Lippman-Schwinger equation. We will do this in an operator form first. Thereafter, we rewrite it in terms of various quantum numbers such as relative momenta, orbital momenta etc. The Schroedinger equation in abstract vector representation is $$ \left( \hat{H}_0 + \hat{V} \right) \vert \psi_n \rangle = E_n \vert\psi_n \rangle. $$ In our case for the two-body problem \( \hat{H}_0 \) is just the kinetic energy. We rewrite it as $$ \left( \hat{H}_0 -E_n \right)\vert\psi_n \rangle =-\hat{V}\vert \psi_n \rangle . $$ We assume that the invers of \( \left( \hat{H}_0 -E_n\right) \) exists and rewrite this equation as $$ \vert\psi_n \rangle =\frac{1}{\left( E_n -\hat{H}_0\right)}\hat{V}\vert \psi_n \rangle . $$