We wish now to derive the Hartree-Fock equations using our second-quantized formalism and study the stability of the equations.
Our ansatz for the ground state of the system is approximated as (this is our representation of a Slater determinant in second quantization)
$$
|\Phi_0\rangle = |c\rangle = a^{\dagger}_i a^{\dagger}_j \dots a^{\dagger}_l|0\rangle.
$$
We wish to determine \( \hat{u}^{HF} \) so that
\( E_0^{HF}= \langle c|\hat{H}| c\rangle \) becomes a local minimum.
In our analysis here we will need Thouless' theorem, which states that
an arbitrary Slater determinant \( |c'\rangle \) which is not orthogonal to a determinant
\( | c\rangle ={\displaystyle\prod_{i=1}^{n}}
a_{\alpha_{i}}^{\dagger}|0\rangle \), can be written as
$$
|c'\rangle=exp\left\{\sum_{a>F}\sum_{i\le F}C_{ai}a_{a}^{\dagger}a_{i}\right\}| c\rangle
$$